Sustainability

Composting: Solution?

More in the Summer 2008 issue

Three years ago, Dickinson College entered the world of biodiesel production in an effort to improve the college's ecological footprint and to provide its students with a hands-on education. Our production, which began with a modest 50-gallon Appleseed reactor, has flourished into a highly successful operation. In 2007, student workers produced more than 2,000 gallons of fuel for campus vehicle use. Our success, however, comes with a problem: we have been struggling to gain control of an ever-growing supply of glycerine.

Although several producers have found creative methods to decrease glycerine stockpiles, very few of these techniques are practical (not every biodiesel maker has the time or desire to craft fifty gallons of soap). That's why our college biodiesel project, with the permission of Pennsylvania's Department of Environmental Protection, decided to conduct some research.

This past fall, Matt Steiman (Dickinson's Biodiesel Production Manager and the SVO forum's "Farmer") and I began to investigate whether composting glycerine is a viable option for responsible small-scale producers. Many popular websites and books suggest that biodiesel glycerine can be composted, but despite thorough searching, we found no documentation of actual composting research. Our goal was to determine what happens biologically and chemically when biodiesel glycerine is added to compost piles. We're still in the process of researching, but we've already found some interesting answers.

We began the experiment by mixing a compost base of cow manure and hay (3:1 ratio). Next, we constructed 3 ft. by 3 ft. piles from 240 gallons of the pre-mixed base. Each pile was then mixed with either 18 gallons (the determined saturation point at which we felt the piles could take no more glycerine without runoff), 13.5 gallons, 9 gallons, or 4.5 gallons of KOH-based glycerine; two piles were left free of glycerine to serve as a control (NOTE: Prior to the experiment, our glycerine was distilled to remove methanol). Piles were then covered with Compostex compost covers to prevent runoff of glycerine into surface and ground waters. During their 12-week maturation period, the piles were turned six times and their temperatures were recorded regularly. At the end of the 12 weeks, samples of the compost were sent to the Woods End Research Laboratory in Mt. Vernon, Maine for testing.

Tests found that carbon to nitrogen ratios and potassium levels increased with the compost's glycerine concentrations, while nitrogen levels decreased. The piles with larger quantities of glycerine were found to stay hotter longer. However, there was no significant difference between the maturity of the piles at the end of the testing period.

The pH of the composts ranged from 8.97 (pile with no glycerine) to 9.71 (pile with 18 gallons of glycerine). In addition, the piles with more glycerine were dryer, denser and they supported larger colonies of a white fungal growth (this fungus is believed to consume fats).

The direct correlation between increased potassium levels with the addition of glycerine indicates that KOH-based glycerine has the potential to increase fertilizer value when added to compost. These results also suggests that NaOH-based glycerine will increase sodium content when added to compost. According to researchers at the Pennsylvania State University, excess sodium is damaging to cropping soil. It may therefore be unwise to compost NaOH-based glycerine.

Because of increased pile temperatures, adding glycerine may also help to kill pathogens and weeds in compost piles.

Research is currently being conducted to address the effect of the compost's high pH on plants. We are trying to determine whether glycerine needs to be neutralized prior to composting, or if the high pH can have a beneficial "liming ability" on acidic soils.

Our research has shown that glycerine can be composted, but there is more to be learned about its affect on the quality of the soil and plant growth. We are currently in the process of finding the answers to these questions. According to Pennsylvania Certified Organic, glycerine is classified as a synthetic product and therefore cannot be used for organic farming in PA. We intend to use the research piles and other biodiesel-waste compost for landscaping applications on campus. 

Alison Dethoff is a senior at Dickinson College, where she studies biology.

Comments

I Am a small scale producer of BIODIESEL for own use... I obviously sit with the same problem.

Please keep me up to date with your progress on this and also forward me some links with more information if possible.

Kind Regards
Warren Adams

I suggest you look to Paul Stamets work, on his website www.fungiperfecti.com for information about the fungal action in your compost. In fact he may have serious answers to the glycerine issue.

HI. Thanks for your interest in the glycerol composting project. We are continuing to persue this topic in our spare time, one compost pile at a time.

Since Ali wrote her article, we've added a temperature sensing data logger to our project hardware... this has allowed us to track the temperatures of the piles 24/7 without having to run out there with a thermometer all day. Dataloggers in two following trials continue to show that the glycerol piles run hotter than the control.

One guess I have is that the glycerol presents some very soluble carbon that the microbes can access readily. This, mixed with any soluble nitrogen material speeds up the decomposition.

What is interesting is that in a pile set that was about 8 months old, the non-glycerol piles seem to be further along. Perhaps the soluble glycerol allowed the bugs to burn up all of the N early on, then they were left with no N to break down the remaining carbon... just speculation at this point.

I did a cucumber seedling trial in last year's compost... cukes grown in a 50/50 blend of compost and potting soil all performed well, regardless of the glycerol content of the original piles. This was after 8 months under cover, so we are confident that the glycerol is not leaching out. This would seem to indicate that the glycerol is not creating any phytotoxicity or salt buildup. Lots of arthropods in all piles as well. This summer I hope to try some worms.

Well, that's where we are at. I am still not using this material on the organic gardens, but I am becoming more confident that in dilute quantities it might be OK for composting without worrying about land toxicity.

The PA DEP has said they will tolerate glycerol composting so long as the methanol has been recovered from the glycerol. Otherwise we would be illegally dumping hazardous waste on the land (gly right out of the reactor has a very low flash point due to 30% methanol content. Distill at ambient pressure up to 240-260 degrees F to bring the flash point up above the Hazmat cutoff).

Learn more at http://www.dickinson.edu/departments/sustainability/biodieselinfo.html#research

Best wishes,
Farmer